Just to let you know on exactly what it is...
During the compression stroke of the engine, the piston moves upward, causing the air / fuel mixture to become compressed. Normally, the spark plug will ignite the mixture, and the force of the explosion then pushes the piston downward etc, etc... Pre-ignition is where the air / fuel mixture ignites prior to the spark plug actually igniting the mixture. The reason it ignites on its own, is because the air / fuel mixture becomes volatile under pressure, and if the pressure is too great, the mixture will combust on its own accord - Pinking / pre-ignition.
Contrary to what most people think, higher RON rated fuel is actually less combustable, hence, when mixed with the same amount of air, it can be pressurised to a greater amount before it will combust on its own accord. (Don't confuse this with the energy that is released from the explosion however...) As high performance engines and racing engines tend to have rather high compression ratios, they require the use of the higher RON rated fuels to stop the possibilities of any pre-ignition taking place. This is typically where the common misconception is made where people think higher RON rated fuels give more power.