I would use filler primer on your wheels . Or high build primer ,is the real name for it . Sand the wheels until the shine is off them ,and are very dull . Bare metalling wheels isnt essential when refurbing them ,I dont know why a lot of people on here are under that misconception.
Spray a first coat leave 15 mins ,then spray a heavier coat until the wheels are covered
Allow a day for them to dry ,then get some 2000 grit wet and dry sandpaper and wet sand the wheels this will make them really smooth for the paint to go on.
Spray the wheels your desired colour with a good few coats ,allow to dry for a day. Then wet sand them the same as you did with the primer ,dry the wheels and apply a lot of laquer .
Lots of people skip the wet sanding but you'll get a better finish if you do it.