Making a good job of one of these heads, in my view is as much what you leave alone as what you change! The finish of the ports is not generally very important, other than to say shiny isn't what you want. By all means have a go yourself, I started as a DIYer; but unless your very flukey or unusually talented, you're unlikely to genuinely make it better without considerable experience.
90% of the talk about heads, relates to "flow", when in reality, these heads flow plenty well enough for most moderate spec engines... the benefits come from smarter attention paid to how the air/fuel and exhaust fluids move around, along with mixture quality and distribution. Likewise, valves have optimum sizes for a spec, rather than just trying to get in the biggest you can.
It all depends what you're trying to achieve though, if you're just trying to imrpove the peak bhp figure, the priorities will be different to trying to create a better power curve that will usually be a better way to improve performance.